Unsaturated aldehydes. Сommunication 1. Properties of the products of the addition of 2 -chloroethanol to acrolein

Unsaturated aldehydes. Сommunication 1. Properties of the products of the addition of 2 -chloroethanol to acrolein Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1964, Volume: 13, Number: 12, Pages: 2094-2098 Pages count : 5 DOI: 10.1007/bf00844222

Authors

Shostakovskii M.F. ¹ , Minakova T.T. ¹ , Sidel'kovskaya F.P. ¹

Affiliations

1	N. D Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

1. The reaction of 2-chloroethanol with acrolein was studied. Acrolein bis-2-chloroethyl acetal (I) and 1,1,3-tris-2-chloroethoxypropane (II) were synthesized. 2. The reaction of (II) with sodium methoxide, ethoxide, and isopropoxide was investigated. One chlorine atom was replaced with formation of 1,3-bis-2-chloroethoxy-1-(2-methoxyethoxy) propane (III), 1,3-bis-2-chloroethoxy-1-(2-ethoxyethoxy) propane (IV), and 1,3-bis-2-chloroethoxy-1-(2-isopropoxyethoxy)propane (V). 3. In the reaction of (II) with sodium butoxide and t-butoxide the elimination of hydrogen chloride occurred with formation of 1,3-bis-2-chloroethoxy-1-(vinyloxy)propane (VI).

Shostakovskii M.F. , Minakova T.T. , Sidel'kovskaya F.P.
Unsaturated aldehydes. Сommunication 1. Properties of the products of the addition of 2 -chloroethanol to acrolein
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1964. V.13. N12. P.2094-2098. DOI: 10.1007/bf00844222 OpenAlex

OpenAlex:

W1989156968

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