Liquid-phase hydrogenation and irreversible catalysis of cyclohexene on a skeletal nickel catalyst Научная публикация
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Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230 |
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| Вых. Данные | Год: 1964, Том: 13, Номер: 8, Страницы: 1318-1321 Страниц : 4 DOI: 10.1007/bf00850326 | ||
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Реферат:
1. In the presence of a skeletal nickel catalyst, the rate of hydrogenation of cyclohexene in dilute alcohol solutions depends on the concentration. At concentrations of 0.5–5.0 millimoles/ml, the reaction proceeds at a constant rate. In the absence of a solvent, the reaction does not proceed. 2. Liquid-phase hydrogenation of cyclohexene on skeletal nickel at 20–60° is accompanied by a reaction of irreversible catalysis. Redistribution of hydrogen also occurs when the cyclohexene is in contact with the catalyst in an atmosphere of nitrogen. 3. The benzene and cyclohexane formed in the process of conversion of cyclohexene lower the reaction rate of the hydrogenation of cyclohexene.
Библиографическая ссылка:
Freidlin L.K.
, Litvin E.F.
, Shafran R.N.
Liquid-phase hydrogenation and irreversible catalysis of cyclohexene on a skeletal nickel catalyst
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1964. V.13. N8. P.1318-1321. DOI: 10.1007/bf00850326 OpenAlex
Liquid-phase hydrogenation and irreversible catalysis of cyclohexene on a skeletal nickel catalyst
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1964. V.13. N8. P.1318-1321. DOI: 10.1007/bf00850326 OpenAlex
Идентификаторы БД:
| OpenAlex: | W1994126408 |
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