Manganа- and rhena-copper carboranes based on the medium-size non-icosahedral 5,6-dicarba-nido-decaborane

Manganа- and rhena-copper carboranes based on the medium-size non-icosahedral 5,6-dicarba-nido-decaborane Научная публикация

Журнал

Journal of Organometallic Chemistry
ISSN: 1872-8561 , E-ISSN: 0022-328X

Вых. Данные

Год: 2020, Том: 911, Номер статьи : 121141, Страниц : DOI: 10.1016/j.jorganchem.2020.121141

Авторы

Balagurova Elena V. ¹ , Dolgushin Fedor M. ¹ , Medvedev Michael G. ^1,2,3,4 , Kononova Elena G. ¹ , Godovikov Ivan A. ¹ , Smol′yakov Alexander F. ^1,5 , Chizhevsky Igor T. ¹

Организации

1	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, 119991, 28 Vavilov Str, Moscow, Russian Federation
2	Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1/3, 119991, Moscow, Russian Federation
3	N. D. Zelinsky Institute of Organic Chemistry of Russian Academy of Sciences, Leninsky Prospect 47, 119991, Moscow, Russian Federation
4	National Research University Higher School of Economics (HSE), Myasnitskaya Str. 20, 101000, Moscow, Russian Federation
5	Faculty of Science, RUDN University, 6 Miklukho-Maklaya Street, 117198, Moscow, Russian Federation

Reaction of the deprotonated medium-size non-icosahedral carborane 5,6-nido-C2B8H12 (1) with Re(CO)5Cl affords tricarbonyl anionic complexes of Re [1,1,1-(CO)3-isonido-1,2,4-ReC2B8H10]- as PPh4- 3a and tmndH- 3b salts (tmnd — N,N,N′,N′-tetramethyl-1,8-diaminonaphtaline). Treatment of [tmndH][1,1,1-(CO)3-isonido-1,2,4-MC2B8H10]- (M = Mn 2b, Re 3b) with the equivalent amount of CuCl and PPh3 in CH2Cl2 leads to formation of two isomers of bimetallic complexes [1,3,7(6)-{Cu(PPh3)}-3,7(6)-μ-H2-1,1,1-(CO)3-isonido-1,2,4-MC2B8H8] (M = Mn 4, Re 5) with two B-H⋯Cu bonds. All newly obtained compounds were characterized by a combination of analytical and multinuclear NMR spectroscopic data and IR spectroscopy. The structures of complexes 3b and 4 were researched by X-ray diffraction studies. The nature of interaction between {Cu(PPh3)} and mangana-carborane fragments was clarified based on the computed electron density critical points (within QTAIM framework) and Density Overlap Regions Indicator (DORI) distributions. Transition state between the two diastereomers of 4 was located, the isomerization rate was found to be of order of 1 s−1.

Balagurova E.V. , Dolgushin F.M. , Medvedev M.G. , Kononova E.G. , Godovikov I.A. , Smol′yakov A.F. , Chizhevsky I.T.
Manganа- and rhena-copper carboranes based on the medium-size non-icosahedral 5,6-dicarba-nido-decaborane
Journal of Organometallic Chemistry. 2020. V.911. 121141 . DOI: 10.1016/j.jorganchem.2020.121141 WOS Scopus OpenAlex

≡ Web of science:	WOS:000517798600009
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