(2-Fluoroallyl)palladium Complexes as Intermediates in Pd-Catalyzed Tsuji-Trost 2-Fluoroallylations: Synthesis and Reactivity

(2-Fluoroallyl)palladium Complexes as Intermediates in Pd-Catalyzed Tsuji-Trost 2-Fluoroallylations: Synthesis and Reactivity Full article

Journal

Journal of Fluorine Chemistry
ISSN: 1873-3328 , E-ISSN: 0022-1139

Output data

Year: 2020, Volume: 236, Article number : 109553, Pages count : DOI: 10.1016/j.jfluchem.2020.109553

Authors

Bobrova Angelina Yu. ^1,2 , Novikov Maxim ¹ , Mezentsev Igor A. ^1,2 , Tomilov Yury V. ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
2	Higher Chemical College of the Russian Academy of Sciences, D. I. Mendeleev University of Chemical Technology of Russia, 125047,Moscow, Russian Federation

The first examples of (2-fluoroallyl)palladium complexes were synthesized, isolated and characterized including chloride dimers, neutral chloride and ionic triflate complexes bearing PPh3 or SPhos as the ligands. Preliminary reactivity patterns indicating strong dependence of the chemoselectivity on "hardness" of the nucleophile and the ligand type were studied.

Bobrova A.Y. , Novikov M. , Mezentsev I.A. , Tomilov Y.V.
(2-Fluoroallyl)palladium Complexes as Intermediates in Pd-Catalyzed Tsuji-Trost 2-Fluoroallylations: Synthesis and Reactivity
Journal of Fluorine Chemistry. 2020. V.236. 109553 . DOI: 10.1016/j.jfluchem.2020.109553 WOS Scopus OpenAlex

≡ Web of science:	WOS:000551145100003
≡ Scopus:	2-s2.0-85086394367
≡ OpenAlex:	W3027918983