Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System

Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System Full article

Journal

Catalysts
ISSN: 2073-4344

Output data

Year: 2023, Volume: 13, Number: 7, Article number : 1126, Pages count : DOI: 10.3390/catal13071126

Authors

Kostromitin Vladislav S. ^1,2 , Levin Vitalij V. ² , Dilman Alexander D. ²

Affiliations

1	Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, 119991 Moscow, Russia
2	N. D. Zelinsky Institute of Organic Chemistry, Leninsky Prosp. 47, 119991 Moscow, Russia

Atom transfer radical addition of bromonitromethane and 1,2-dibromotetrafluoroethane to alkenes is described. The reaction is performed under blue light irradiation using two catalysts: 4CzIPN and manganese (II) bromide. The cyanoarene photocatalyst serves for the redox activation of starting organic bromide, while the manganese salt facilitates the trapping of the alkyl radical with the formation of the carbon–bromine bond.

Kostromitin V.S. , Levin V.V. , Dilman A.D.
Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System
Catalysts. 2023. V.13. N7. 1126 . DOI: 10.3390/catal13071126 WOS Scopus OpenAlex

Web of science:	WOS:001035144600001
Scopus:	2-s2.0-85166354186
OpenAlex:	W4384758647

DB	Citing
OpenAlex	2
Scopus	3
Web of science	2