Interaction between Sodium and Dimethylacetamide As the Cause of Instability in the Operation of a Sodium-Ion Battery Full article
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Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X |
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| Output data | Year: 2020, Volume: 94, Number: 6, Pages: 1276-1279 Pages count : 4 DOI: 10.1134/s0036024420060308 | ||||||
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Abstract:
The presence of dimethylacetamide (DMAA) in the composition of electrolytes of a sodium-ion battery destroys the passive film on electrodes and results in a number of reactions not connected with the electrochemical process that must be considered in developing such batteries. Introducing DMAA into the composition of a battery electrolyte greatly improves the conductivity of the polymeric membrane that separates the cathode and anode spaces. However, it is established that in the presence of sodium metal, anhydrous DMAA undergoes Claisen-like self-condensation with subsequent reactions. IR spectroscopy is used to explain the causes of the electrochemical instability of sodium perchlorate solutions in mixed solvents containing DMAA.
Cite:
Vedenyapina M.D.
, Kulova T.L.
, Kudryashova Y.O.
, Skundin A.M.
, Malyshev O.R.
, Glukhov L.M.
Interaction between Sodium and Dimethylacetamide As the Cause of Instability in the Operation of a Sodium-Ion Battery
Russian Journal of Physical Chemistry A. 2020. V.94. N6. P.1276-1279. DOI: 10.1134/s0036024420060308 WOS Scopus OpenAlex
Interaction between Sodium and Dimethylacetamide As the Cause of Instability in the Operation of a Sodium-Ion Battery
Russian Journal of Physical Chemistry A. 2020. V.94. N6. P.1276-1279. DOI: 10.1134/s0036024420060308 WOS Scopus OpenAlex
Identifiers:
| Web of science: | WOS:000537451900032 |
| Scopus: | 2-s2.0-85085699611 |
| OpenAlex: | W3033169645 |