Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media

Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media Full article

Journal

Doklady Chemistry
ISSN: 1608-3113 , E-ISSN: 0012-5008

Output data

Year: 2021, Volume: 500, Number: 2, Pages: 209-212 Pages count : 4 DOI: 10.1134/s0012500821100037

Authors

Ivanov R.E. ¹ , Zharkov M.N. ¹ , Zlotin S.G. ¹

Affiliations

1	Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, Russia

For the first time the reactions of radical nitration of alkenes and oxiranes with nitrogen dioxide in the liquid and supercritical carbon dioxide (sc-CO2) media were carried out. Using octene-1, styrene, and their derivatives as examples, the effectiveness of the developed method for obtaining valuable 1,2-functionalized products, including nitroalcohols, dinitroalkanes, and nitronitrates have been shown. Due to the application of sc-CO2, the proposed method compares favorably with known analogs by the absence of by-products and waste organic solvents, as well as lesser fire and explosion hazards.

Ivanov R.E. , Zharkov M.N. , Zlotin S.G.
Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media
Doklady Chemistry. 2021. V.500. N2. P.209-212. DOI: 10.1134/s0012500821100037 WOS Scopus OpenAlex

Web of science:	WOS:000753859800003
Scopus:	2-s2.0-85124841486
OpenAlex:	W4211243860

DB	Citing
OpenAlex	3
Scopus	3
Web of science	3