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Some reactions of 3,3,3- and 1,1,3-trichloropropenes Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230
Вых. Данные Год: 1954, Том: 3, Номер: 2, Страницы: 209-214 Страниц : 6 DOI: 10.1007/bf01177616
Авторы Nesmeyanov A.N. 1 , Zakharkin L.I. 1 , Kost V.N. 1 , Freidlina R.Kh. 1
Организации
1 N. D. Zelinsky Institute of organic Chemistry of the USSR Academy of Sciences, USSR

Реферат: 1. A study has been made of the action of diethylamine, sodiomalonic ester, sodium sulfide, and sodium methoxide on 3,3,3-trichloropropene and 1,1,3-trichloropropene. It has been shown that in all cases, the reaction with 3,3,3-trichloropropene is accompanied by allyl rearrangement, so that the products are the same as those obtained by the action of the same reagents on 1,1,3-trichloropropene. 2. A study has been made of the action of organomagnesium compounds on 3,3,3- and 1,1,3-trichloropropenes. It has been shown that the alkylation of 3,3,3-trichloropropene is accompanied by allyl rearrangement. 3. A study has been made of the action of cuprous cyanide on 3,3,3- and 1,1,3-trichloropropenes, and it has been shown that in the case of 3,3,3-trichloropropene this reaction Is accompanied by allyl rearrangement. 4. It has been found that in presence of AICI3 polyhaloethylenes unite with both 3,3,3-trichloropropene and 1,1,3-trichloropropene.
Библиографическая ссылка: Nesmeyanov A.N. , Zakharkin L.I. , Kost V.N. , Freidlina R.K.
Some reactions of 3,3,3- and 1,1,3-trichloropropenes
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1954. V.3. N2. P.209-214. DOI: 10.1007/bf01177616 OpenAlex
Идентификаторы БД:
OpenAlex: W2065026151
Цитирование в БД: Пока нет цитирований
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