Investigations of the interaction between vinyl and polyfunctional compounds. Communication 3. Reaction of glycerol trivinyl ether with ethylene glycol and 1,4-butanediol.

Investigations of the interaction between vinyl and polyfunctional compounds. Communication 3. Reaction of glycerol trivinyl ether with ethylene glycol and 1,4-butanediol. Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1954, Volume: 3, Number: 4, Pages: 583-587 Pages count : 5 DOI: 10.1007/bf01172703

Authors

Shostakovsky M.F. ¹ , Zhebrovsky V.V. ¹ , Medelyanovskaya M.A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

1. The reaction between glycerol trivinyl ether and ethylene glycol was studied at molar and equivalent ratios (1:1 and 2:3) and between glycerol trivinyl ether and 1,4-butanediol at molar ratio (1:1). 2. Reaction between glycerol trivinyl ether and ethylene glycol and 1,4-butanediol in molar ratio leads to formation of cyclic acetals of the glycols (III) and (XI), the isomeric glycerol acetals (VIII) and (IX) and glycerol triacetal (X). Equivalent proportions of glycerol trivinyl ether and ethylene glycol yielded ethylene glycol acetal (III), glycerol 1,2-acetal (VIII) and a very mind amount of glycerol 1,3-acetal (IX). 3. The formation of cyclic acetals of glycols and glycerol is accounted for by tautomerism of the corresponding acetals.

Shostakovsky M.F. , Zhebrovsky V.V. , Medelyanovskaya M.A.
Investigations of the interaction between vinyl and polyfunctional compounds. Communication 3. Reaction of glycerol trivinyl ether with ethylene glycol and 1,4-butanediol.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1954. V.3. N4. P.583-587. DOI: 10.1007/bf01172703 OpenAlex

OpenAlex:

W2312240739

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