Investigation of the mechanism of the cyclization reaction with the help of deuterium Научная публикация
| Журнал |
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230 |
||
|---|---|---|---|
| Вых. Данные | Год: 1954, Том: 3, Номер: 5, Страницы: 743-746 Страниц : 4 DOI: 10.1007/bf01170117 | ||
| Авторы |
|
||
| Организации |
|
Реферат:
1. Under the action of deuterophosphoric acid the dienone (VIII) cyclizes to the monodeutero-cyclopentenone (IXa) which, an ozonization, gives the deutero-ketoacid (X); oxidation of the latter with bromide lye leads to the detero-dicarboxylic acid (XI). 2. The dienone (VIII) and the cyclic ketone (IX) practically do not exchange their hydrogens for deuterium in the conditions of cyclization and, consequently, the entry of deuterium into the molecule of the cyclic ketone only takes place in the instant of its cyclization. 3. The results obtained are convincing evidence of the correctness of the proposed ionic mechanism of this cyclization reaction.
Библиографическая ссылка:
Kursanоv D.N.
, Parnes Z.N.
, Zaretskaya I.I.
, Nazarov I.N.
Investigation of the mechanism of the cyclization reaction with the help of deuterium
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1954. V.3. N5. P.743-746. DOI: 10.1007/bf01170117 OpenAlex
Investigation of the mechanism of the cyclization reaction with the help of deuterium
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1954. V.3. N5. P.743-746. DOI: 10.1007/bf01170117 OpenAlex
Идентификаторы БД:
| OpenAlex: | W2312697266 |
Цитирование в БД:
Пока нет цитирований