Synthesis of Sulfur-Containing Heterocycles by Electrophilic Addition Reactions of Disulfur Dichloride

Synthesis of Sulfur-Containing Heterocycles by Electrophilic Addition Reactions of Disulfur Dichloride Review

Journal

Chemistry of Heterocyclic Compounds
ISSN: 1573-8353 , E-ISSN: 0009-3122

Output data

Year: 2020, Volume: 56, Number: 7, Pages: 837-847 Pages count : 11 DOI: 10.1007/s10593-020-02740-2

Authors

Rakitin Oleg А. ^1,2

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
2	Nanotechnology Research and Education Center, South Ural State University, Chelyabinsk, Russia

This review compiles and summarizes approaches to the preparation of heterocyclic systems containing sulfur atoms based on the reactions of disulfur dichloride which acts as an electrophilic reagent. It is shown that as a result of these transformations heterocycles with different numbers of sulfur atoms can be synthesized: 1,2,5-thiadiazoles, 1,2- and 1,4-thiazines, 1,2-dithiols, 1,2,3-dithiazoles, 1,2,3,4,5-pentathiepines, 1,2,3,4,5,6,7-heptathiocanes, and many others. The yields of the products of these reactions depend to a significant extent on the ratio of the reactants, the nature of the solvent, the base used, and the temperature. The exceptional role of disulfur dichloride in the synthesis of various sulfur-containing heterocycles is shown.

Rakitin O.А.
Synthesis of Sulfur-Containing Heterocycles by Electrophilic Addition Reactions of Disulfur Dichloride
Chemistry of Heterocyclic Compounds. 2020. V.56. N7. P.837-847. DOI: 10.1007/s10593-020-02740-2 WOS Scopus OpenAlex

Web of science:	WOS:000561986600006
Scopus:	2-s2.0-85089745760
OpenAlex:	W3080298366

DB	Citing
OpenAlex	10
Scopus	10
Web of science	12