Efficient tunable approach for 5-(hydroxymethyl)furfural and 2,5-diformylfuran production from fructose in DMSO with bromide catalysis

Efficient tunable approach for 5-(hydroxymethyl)furfural and 2,5-diformylfuran production from fructose in DMSO with bromide catalysis Full article

Journal

Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905

Output data

Year: 2024, Volume: 186, Article number : 106831, Pages count : DOI: 10.1016/j.catcom.2023.106831

Authors

Kolykhalov Denis A. ¹ , Golysheva Anastasia N. ¹ , Karlinskii Bogdan Ya. ^1,2

Affiliations

1	BioChemTech Research Center, Tula State University, pr. Lenina 92, Tula 300012, Russia
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, pr. Leninsky 47, Moscow 119991, Russia

This work describes a simple method for the preparation of 5-hydroxymethylfurfural (HMF) by dehydrating fructose in DMSO, either with the use of an affordable catalyst or in a catalyst-free manner. This process can be accompanied, under harsh conditions, by the bromide-catalyzed Kornblum oxidation of the hydroxyl group by the solvent, resulting in the formation of 2,5-diformylfuran (DFF). The optimized techniques presented in this study can serve as a foundation for the production of valuable biobased furanic platform chemicals from renewable sources in any laboratory, stimulating the development of sustainable chemistry and research in related fields worldwide.

Kolykhalov D.A. , Golysheva A.N. , Karlinskii B.Y.
Efficient tunable approach for 5-(hydroxymethyl)furfural and 2,5-diformylfuran production from fructose in DMSO with bromide catalysis
Catalysis Communications. 2024. V.186. 106831 . DOI: 10.1016/j.catcom.2023.106831 WOS Scopus OpenAlex

Web of science:	WOS:001154048700001
Scopus:	2-s2.0-85181772460
OpenAlex:	W4390582874

DB	Citing
OpenAlex	3
Scopus	3
Web of science	3