Catalytic vapor-phase hydrogenation of isopropylcyclopropane and isoproplnylcyclopropane

Catalytic vapor-phase hydrogenation of isopropylcyclopropane and isoproplnylcyclopropane Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1956, Volume: 5, Number: 11, Pages: 1431-1435 Pages count : 5 DOI: 10.1007/bf01177710

Authors

Kazansky В.A. ¹ , Lukina M.Yu. ¹ , Malyshev A.I. ¹

Affiliations

1	N. D. Zelinsky institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

1. A study was made of the hydrogenation of isopropyl- and isopropenyl-cyclopropanes-over palladized and platinized charcoals at 120° at a space velocity of 0.2. 2. Substantial differences were found in the behaviors of the two hydrocarbons in the reaction of catalytic hydrogenation: irrespective of the identity of the catalyst, isopropylcyclopropane is converted into 2,3-dimethyl-butane; in presence of palladium isopropenylcyclopropane is converted into 2-methylpentane, and in presence, of platinum it is-converted into a mixture of 2-methylpentane and 2,3-dimethylbutane.

Kazansky В.A. , Lukina M.Y. , Malyshev A.I.
Catalytic vapor-phase hydrogenation of isopropylcyclopropane and isoproplnylcyclopropane
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1956. V.5. N11. P.1431-1435. DOI: 10.1007/bf01177710 OpenAlex

OpenAlex:

W2095287974

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