Synthesis of 3,3-disubstituted 1-(1H-tetrazol-5-ylmethoxy)triaz-1-ene 2-oxides

Synthesis of 3,3-disubstituted 1-(1H-tetrazol-5-ylmethoxy)triaz-1-ene 2-oxides Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2020, Volume: 69, Number: 1, Pages: 105-109 Pages count : 5 DOI: 10.1007/s11172-020-2729-3

Authors

Smirnov G.A. ¹ , Gordeev P.B. ¹ , Luk’yanov O.A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

3,3-Disubstituted 1-(tetrazol-5-ylmethoxy)triaz-1-ene 2-oxides were synthesized by heating the corresponding 1-cyanomethyl derivatives with sodium azide in DMF. The starting 1-cyanomethyl derivatives were prepared by either the reaction of chloroacetonitrile with the salts of 3,3-disubstituted 1-hydroxytriaz-1-ene 2-oxides or successive transformations of these salts to 1-methoxycarbonylmethyl and 1-carbamoylmethyl derivatives and further to 1-cyanomethyl derivatives.

Smirnov G.A. , Gordeev P.B. , Luk’yanov O.A.
Synthesis of 3,3-disubstituted 1-(1H-tetrazol-5-ylmethoxy)triaz-1-ene 2-oxides
Russian Chemical Bulletin. 2020. V.69. N1. P.105-109. DOI: 10.1007/s11172-020-2729-3 WOS Scopus OpenAlex

≡ Web of science:	WOS:000524864100012
≡ Scopus:	2-s2.0-85083055051
≡ OpenAlex:	W3015300105