Synthesis of hydroxy-containing terarylenes with pyrazole and allomaltol fragments

Synthesis of hydroxy-containing terarylenes with pyrazole and allomaltol fragments Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2020, Volume: 69, Number: 4, Pages: 758-762 Pages count : 5 DOI: 10.1007/s11172-020-2829-0

Authors

Komogortsev A.N. ¹ , Melekhina V.G. ¹ , Lichitsky B.V. ¹ , Dudinov A.A. ¹ , Fakhrutdinov A.N. ¹ , Krayushkin M.M. ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow (Russian Federation)

A convenient method for the synthesis previously unknown hydroxy-containing aryl(hetaryl)-ethenes (terarylenes) with a pyrazole bridge was elaborated, which is based on the reaction of hydrazines with the products of condensation of allomaltol with arylglyoxals. Two isomeric pyrazoles can be formed depending on the nature of substituents in the hydrazine molecule. The protocols for identification of obtained products were suggested based on 2D 1H-13C HMBC NMR spectroscopy and 1D selective NOESY experiments (SELNOGP).

Komogortsev A.N. , Melekhina V.G. , Lichitsky B.V. , Dudinov A.A. , Fakhrutdinov A.N. , Krayushkin M.M.
Synthesis of hydroxy-containing terarylenes with pyrazole and allomaltol fragments
Russian Chemical Bulletin. 2020. V.69. N4. P.758-762. DOI: 10.1007/s11172-020-2829-0 WOS Scopus OpenAlex

Web of science:	WOS:000528834400019
Scopus:	2-s2.0-85083970609
OpenAlex:	W3020283943

DB	Citing
OpenAlex	7
Scopus	6