Chloroplatinic acid as a catalyst for the addition of silanes containing silicon-attached hydrogen to unsaturated compounds

Chloroplatinic acid as a catalyst for the addition of silanes containing silicon-attached hydrogen to unsaturated compounds Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1958, Volume: 7, Number: 2, Pages: 238-240 Pages count : 3 DOI: 10.1007/bf01168537

Authors

Ponomarenko V.A. ¹ , Cherkaev V.G. ¹ , Petrov A.D. ¹ , Zadorozhnyi N.A. ¹

Affiliations

1	N. D, Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

1. Addition reactions of CH3SiHCl2 were carried out in presence of chloroplatinic acid with ethylene, propene, and acetylene at room temperature and with CH2 = CF2 and CF2 = CF2 at 160°. 2. It was shown that, as compared with reaction in presence of platinum on carriers, in the case of CH2 = CF2 the yield of addition products was increased by a factor of 3–4. whereas in the case of CH2=CH2, CH2 = = CH- CH3 and CH ≡ CH almost quantitative yields were obtained.

Ponomarenko V.A. , Cherkaev V.G. , Petrov A.D. , Zadorozhnyi N.A.
Chloroplatinic acid as a catalyst for the addition of silanes containing silicon-attached hydrogen to unsaturated compounds
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1958. V.7. N2. P.238-240. DOI: 10.1007/bf01168537 OpenAlex

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