Action of raney nickel on ethers of the thiophene series

Action of raney nickel on ethers of the thiophene series Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1957, Volume: 6, Number: 2, Pages: 229-234 Pages count : 6 DOI: 10.1007/bf01170558

Authors

Goldfarb Ya.L. ¹ , Konstantinov P.A. ¹

Affiliations

1	N. D. Zelinsky institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

1. By the action of sodium alkoxides on chloromethyl derivatives of thiophene and its homologs, the following ethers were prepared: isopentyl 2-thenyl ether, 2-tert-butyl-3,4-bismethoxymethyl-5-methylthiopheue, 2-(5-methyl-2-thienyl)ethyl thenyl ether, 2,5-di-tert-butyl-3,4-bismetboxymethylthiophene. 2. It was shown that Raney nickel reacts with ethers of the thiophene series with splitting of the C-S link and formation of aliphatic ethers. 3. The following ethers were obtained: tsopentyl pentyl ether, heptyl pentyl ether, and 4,5-bismethoxymethyl-2,2-dimethylheptane. 4. Preliminary experiments on the action of Raney nickel on acetals of the thiophene series enables us to conclude that it is possible to retain the acetal grouping while eliminating sulfur.

Goldfarb Y.L. , Konstantinov P.A.
Action of raney nickel on ethers of the thiophene series
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1957. V.6. N2. P.229-234. DOI: 10.1007/bf01170558 OpenAlex

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