Dehydrogenation of butane-butene mixtures investigated with the aid of C14

Dehydrogenation of butane-butene mixtures investigated with the aid of C14 Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1957, Volume: 6, Number: 2, Pages: 167-175 Pages count : 9 DOI: 10.1007/bf01170549

Authors

Balandin A.A. ^1,2 , Nelman M.B. ^1,2 , Bogdanova O.K. ^1,2 , isagulyants G.V. ^1,2 , Shcheglova A.P. ^1,2 , Popov E.I. ^1,2

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR
2	Institute of Chemical Physics of the Academy of Sciences of the USSR, USSR

1. It was shown that in the dehydrogenation of butane-butene mixtures over a chromium oxide catalyst the formation of butadiene proceeds by the dehydrogenation, of butene; practically no direct conversion of butane into butadiene occurs. 2. t was found that the rate constant for the desorption of butene is greater than that for its dehydrogenation, a fact which is important in principle for the theory of dehydrogenational catalysis. 3. esults were obtained which indicate that a reaction of redistribution of hydrogen occurs between butane and butene, consisting in simultaneous hydrogenation of butene and dehydrogenation of butane proceeding together with the general dehydrogenation reaction. This new reaction is on the one hand allied to disproportionation of hydrogen, and on the other to isotopic exchange of hydrogen.

Balandin A.A. , Nelman M.B. , Bogdanova O.K. , isagulyants G.V. , Shcheglova A.P. , Popov E.I.
Dehydrogenation of butane-butene mixtures investigated with the aid of C14
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1957. V.6. N2. P.167-175. DOI: 10.1007/bf01170549 OpenAlex

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