Hydrogenation of cyclopentadiene in binary mixtures with unsaturated hydrocarbons over palladium and platinum blacks

Hydrogenation of cyclopentadiene in binary mixtures with unsaturated hydrocarbons over palladium and platinum blacks Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1957, Volume: 6, Number: 5, Pages: 555-559 Pages count : 5 DOI: 10.1007/bf01169270

Authors

Freidlin L.Kh. ¹ , Polkovnikov B.D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences of the USSR, Russia

1. A study was made of the selectivity of the hydrogenation of cyclopentadiene into cyclopentene in binary mixtures with unsaturated hydrocarbons in presence of palladium and platinum blacks. 2. It was found that, like Raney nickel. palladium black brings about selective hydrogenation of cyclopentadiene in its binary mixture with cyclohexene, but nonselective hydrogenation in mixtures with styrene. Palladium black differs from Raney nickel in that it does not bring about selective hydrogenation of cyclopentadiene in its mixtures with diphenylacetylene. In presence of platinum black, cyclopentadiene is not hydrogenated selectively in binary mixtures with cyclopentene and 1-octene.

Freidlin L.K. , Polkovnikov B.D.
Hydrogenation of cyclopentadiene in binary mixtures with unsaturated hydrocarbons over palladium and platinum blacks
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1957. V.6. N5. P.555-559. DOI: 10.1007/bf01169270 OpenAlex

OpenAlex:

W2062100546

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