Preparation and properties of some alkyldeuteriosilanes

Preparation and properties of some alkyldeuteriosilanes Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1958, Volume: 7, Number: 1, Pages: 47-51 Pages count : 5 DOI: 10.1007/bf01170860

Authors

Ponomarenko V.A. ¹ , Egorov Iu.P. ¹ , Vzenkova G.Ia. ¹

Affiliations

1	N. D, Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

1. It was shown that alkyldeuteriosilanes can be prepared from the corresponding alkylchlorosilanes by reducing them with LiD. 2. Fine new alkyldeuteriosilanes were prepared, and some of their physical properties were studied. It was shown that the frequencies of the valence vibrations of Si—D fall in the region 1530–1570 cm-1 and are lowered by reduction of the number of D atoms attached to Si. It was found that the refraction of the Si —D bond is 3.23 ml/ mole.

Ponomarenko V.A. , Egorov I.P. , Vzenkova G.I.
Preparation and properties of some alkyldeuteriosilanes
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1958. V.7. N1. P.47-51. DOI: 10.1007/bf01170860 OpenAlex

≡ OpenAlex:

W1984251413