Vapor-phase hydrolysis of halobenzenes over a promoted phosphate catalyst

Vapor-phase hydrolysis of halobenzenes over a promoted phosphate catalyst Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1958, Volume: 7, Number: 2, Pages: 137-142 Pages count : 6 DOI: 10.1007/bf01168514

Authors

Freidlin L.Kh. ¹ , Balandin A.A. ¹ , Fridman G.A. ¹

Affiliations

1	N. D, Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

1. The vapor-phase hydrolysis of halobenzenes over a phosphate catalyst promoted with cupric chloride was investigated. 2. It was shown that, as in the presence of silica gel, in the presence of tricalcium phosphate the hydrolysis of chlorobenzene is promoted by cupric chloride. 3. It was found that the reactivities of halobenzenes in the investigated reaction fall in the same order as in presence of silica gel. 4. The question of the ratio between total and active surface in silica gel and phosphate catalysts was discussed. The number of active sites in the catalyst was estimated.

Freidlin L.K. , Balandin A.A. , Fridman G.A.
Vapor-phase hydrolysis of halobenzenes over a promoted phosphate catalyst
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1958. V.7. N2. P.137-142. DOI: 10.1007/bf01168514 OpenAlex

≡ OpenAlex:

W1982108839