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Steric factor in electrophilic substitution reactions of aromatic hydrocarbons Full article

Journal Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230
Output data Year: 1957, Volume: 6, Number: 7, Pages: 861-869 Pages count : 9 DOI: 10.1007/bf01160231
Authors Nazarov I.N. 1 , Semenovsky A.V. 1
Affiliations
1 N. D. Zelinsky institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

Abstract: In supplementation of previous work on halomethylation reactions, the nitration, chlorination, bromination, and iodination of toluene, ethylbenzene, and eumene were investigated. By the method of oxidizing the derivatives formed, the relative amounts of o- and p-isomers were determined quantitatively, and the results reveal the steric effects of substituents in the aromatic nucleus on orientation in all of the above-mentioned electrophilic substitution reactions.
Cite: Nazarov I.N. , Semenovsky A.V.
Steric factor in electrophilic substitution reactions of aromatic hydrocarbons
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1957. V.6. N7. P.861-869. DOI: 10.1007/bf01160231 OpenAlex
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