Synthesis of benzannelated five-membered heteroaromatic compounds from 2,4,6-trinitrotoluene

Synthesis of benzannelated five-membered heteroaromatic compounds from 2,4,6-trinitrotoluene Full article

Journal

Arkivoc
ISSN: 1551-7012 , E-ISSN: 1551-7004

Output data

Year: 2009, Number: 4, Pages: 88-114 Pages count : 27 DOI: 10.3998/ark.5550190.0010.409

Authors

Bastrakov Maxim A. ¹ , Starosotnikov Alexey M. ¹ , Shevelev Svyatoslav A. ¹

Affiliations

1	Institute of Organic Chemistry RAS, Leninsky prospect 47, Moscow,119991, Russia

Methods for the synthesis of five-membered benzannelated heterocyclic compounds from the military explosive 2,4,6-trinitrotoluene (TNT) are summarised. The general approach concerns the transformation of the TNT methyl group followed by either intramolecular substitution of the ortho-nitro group or regioselective substitution of the ortho-nitro group by an appropriate nucleophile and subsequent cyclization.

Bastrakov M.A. , Starosotnikov A.M. , Shevelev S.A.
Synthesis of benzannelated five-membered heteroaromatic compounds from 2,4,6-trinitrotoluene
Arkivoc. 2009. N4. P.88-114. DOI: 10.3998/ark.5550190.0010.409 WOS Scopus OpenAlex

Web of science:	WOS:000265191600009
Scopus:	2-s2.0-63549116472
OpenAlex:	W2950920761

DB	Citing
OpenAlex	4
Web of science	7
Scopus	5