Novel Convenient Method for the Synthesis of N,N-Bis(trimethylsilyloxy)enamines

Novel Convenient Method for the Synthesis of N,N-Bis(trimethylsilyloxy)enamines Full article

Journal

Synthesis
ISSN: 1437-210X , E-ISSN: 0039-7881

Output data

Year: 1998, Volume: 1998, Number: 02, Pages: 181-185 Pages count : 5 DOI: 10.1055/s-1998-2019

Authors

Dilman A.D. ¹ , Tishkov A.A. ¹ , Lyapkalo I.M. ¹ , Ioffe S.L. ¹ , Strelenko Yu.A. ¹ , Tartakovsky V.A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation

Both primary and secondary aliphatic nitro compounds 1 were found to react with two equivalents of bromotrimethylsilane in the presence of triethylamine followed by aqueous workup to give appropriate N,N-bis(trimethylsilyloxy)enamines 3 in good isolated yields. Products 3, starting from some secondary and/or sterically hindered compounds 1, are synthesized from the corresponding silyl nitronates 2.

Dilman A.D. , Tishkov A.A. , Lyapkalo I.M. , Ioffe S.L. , Strelenko Y.A. , Tartakovsky V.A.
Novel Convenient Method for the Synthesis of N,N-Bis(trimethylsilyloxy)enamines
Synthesis. 1998. V.1998. N02. P.181-185. DOI: 10.1055/s-1998-2019 OpenAlex

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