Alkylation of furancarboxylic acid derivatives with alkenes catalyzed by nickel complexes with N-heterocyclic carbenes

Alkylation of furancarboxylic acid derivatives with alkenes catalyzed by nickel complexes with N-heterocyclic carbenes Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2023, Volume: 72, Number: 8, Pages: 1746-1752 Pages count : 7 DOI: 10.1007/s11172-023-3956-1

Authors

Shepelenko K.E. ¹ , Soliev S.B. ¹ , Nikolaeva K.A. ¹ , Minyaev M.E. ² , Chernyshev V.M. ³

Affiliations

1	M. I. Platov South-Russian State Polytechnic University (NPI), Novocherkassk, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
3	M. I. Platov South-Russian State Polytechnic University (NPI), 132 ul. Prosveshcheniya, 346428, Novocherkassk, Russian Federation

An efficient catalytic system based on commercially available nickel source (NiCp2), N-heterocyclic carbene, and a reducing agent (HCOONa) for selective C(5)H-alkylation of amides and esters of 2-furancarboxylic acid with alkenes of various structures was developed. A series of new previously undescribed 5-alkyl derivatives of 2-furancarboxylic acid were synthesized.

Shepelenko K.E. , Soliev S.B. , Nikolaeva K.A. , Minyaev M.E. , Chernyshev V.M.
Alkylation of furancarboxylic acid derivatives with alkenes catalyzed by nickel complexes with N-heterocyclic carbenes
Russian Chemical Bulletin. 2023. V.72. N8. P.1746-1752. DOI: 10.1007/s11172-023-3956-1 WOS Scopus OpenAlex

≡ Web of science:	WOS:001062790500003
≡ Scopus:	2-s2.0-85169671354
≡ OpenAlex:	W4386450294