Synthesis of ferrocene-containing phosphonous and phosphinic acids based on alkenylferrocenes

Synthesis of ferrocene-containing phosphonous and phosphinic acids based on alkenylferrocenes Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2023, Volume: 72, Number: 8, Pages: 1849-1854 Pages count : 6 DOI: 10.1007/s11172-023-3968-x

Authors

Prishchenko A.A. ¹ , Livantsov M.V. ¹ , Novikova O.P. ¹ , Livantsova L.I. ¹ , Baranin S.V. ² , Bubnov Yu.N. ^3,2

Affiliations

1	M. V. Lomonosov Moscow State University, Chemical Department, Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
3	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation

A convenient synthesis of functionalized phosphonous and phosphinic acid derivatives based on alkenylferrocenes has been developed. Radical addition of bis(trimethylsiloxy)-phosphine to vinyl- and isopropenylferrocenes proceeds regioselectively to give new 2-ferrocene-containing alkylphosphonites. Subsequent aminomethylation of these phosphonites affords various phosphinic acid derivatives. The obtained compounds are of interest as promising biologically active substances and effective ligands.

Prishchenko A.A. , Livantsov M.V. , Novikova O.P. , Livantsova L.I. , Baranin S.V. , Bubnov Y.N.
Synthesis of ferrocene-containing phosphonous and phosphinic acids based on alkenylferrocenes
Russian Chemical Bulletin. 2023. V.72. N8. P.1849-1854. DOI: 10.1007/s11172-023-3968-x WOS Scopus OpenAlex

≡ Web of science:	WOS:001062790500015
≡ Scopus:	2-s2.0-85169700239
≡ OpenAlex:	W4386450297