The formation of tetracyclo[7.2.1.02,5.02,8]dodeca-6,10-dienes under conditions of thermal isomerization of spiro[2.4]hepta-4,6-diene into bicyclo[3.2.0]hepta-1,3-diene Full article
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Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285 |
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| Output data | Year: 1993, Volume: 42, Number: 1, Pages: 118-123 Pages count : 6 DOI: 10.1007/bf00699990 | ||
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Abstract:
The formation of the novel hydrocarbons, tetracyclo[7.2.1.02,5.02,8]dodecadienes, as a result of thermal isomerization of spiro[2.4]hepta-4,6-diene into bicyclo[3.2.0]hepta-1,3-diene and its capture by 1,3-dienes is demonstrated. The conditions of thermal isomerization and dimerization of the spiroheptadiene are studied. Cyclopropanation of the polycyclic dienes formed by diazomethane in the presence of Pd-catalysts was accomplished, and occured solely through the norbornene double bond.
Cite:
Tomilov Y.V.
, Kostitsyn A.B.
, Shulishov E.V.
, Nefedov O.M.
The formation of tetracyclo[7.2.1.02,5.02,8]dodeca-6,10-dienes under conditions of thermal isomerization of spiro[2.4]hepta-4,6-diene into bicyclo[3.2.0]hepta-1,3-diene
Russian Chemical Bulletin. 1993. V.42. N1. P.118-123. DOI: 10.1007/bf00699990 WOS Scopus OpenAlex
The formation of tetracyclo[7.2.1.02,5.02,8]dodeca-6,10-dienes under conditions of thermal isomerization of spiro[2.4]hepta-4,6-diene into bicyclo[3.2.0]hepta-1,3-diene
Russian Chemical Bulletin. 1993. V.42. N1. P.118-123. DOI: 10.1007/bf00699990 WOS Scopus OpenAlex
Identifiers:
| ≡ Web of science: | WOS:A1993MM95700028 |
| ≡ Scopus: | 2-s2.0-34249764042 |
| ≡ OpenAlex: | W2041937374 |