A Straightforward Strategy for the Preparation of Diverse BODIPY Functionalized with Polyamines and Polyoxyethylenes**

A Straightforward Strategy for the Preparation of Diverse BODIPY Functionalized with Polyamines and Polyoxyethylenes** Full article

Journal

ChemistrySelect
ISSN: 2365-6549

Output data

Year: 2022, Volume: 7, Number: 6, Article number : e202104210, Pages count : DOI: 10.1002/slct.202104210

Authors

Uvarov Denis Y. ¹ , Gorbatov Sergey A. ¹ , Kolokolova Marya K. ¹ , Kozlov Mikhail A. ¹ , Kolotirkina Natalya G. ¹ , Zavarzin Igor V. ¹ , Goze Christine ² , Denat Franck ² , Volkova Yulia A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., Moscow, 119991, Russia
2	Institut de Chimie Moléculaire de l'Université de Bourgogne, ICMUB, UMR CNRS 6302, Université Bourgogne Franche-Comté, 9, avenue Alain Savary, 21078 Dijon, France

Novel derivatives of 4,4-difluoro-1,3,5,7,8-pentamethyl-4-bora-3a,4a-diaza-s-indacene (BODIPY) functionalized at the meso-position with polyamines and polyoxyethylenes were synthesized through single-step condensation of fluorogenic 8-CH2Cl-substituted BODIPY and corresponding amines. The systematic spectroscopic characterization (UV-Vis, fluorescence) of stable in storage dyes bearing polyoxyethylene substituents was carried out. One compound showed promise for UV-Vis and “off-on” fluorescence Cu2+ detection in acetonitrile solutions. The ligand detects Cu2+ ions selectively in the presence of eighteen different alkaline earth metal cations.

Uvarov D.Y. , Gorbatov S.A. , Kolokolova M.K. , Kozlov M.A. , Kolotirkina N.G. , Zavarzin I.V. , Goze C. , Denat F. , Volkova Y.A.
A Straightforward Strategy for the Preparation of Diverse BODIPY Functionalized with Polyamines and Polyoxyethylenes**
ChemistrySelect. 2022. V.7. N6. e202104210 . DOI: 10.1002/slct.202104210 WOS Scopus OpenAlex

≡ Web of science:	WOS:000811732700008
≡ Scopus:	2-s2.0-85125067594
≡ OpenAlex:	W4211225613