Synthesis of 4-Nitroisoxazole-Based Energetic Materials

Synthesis of 4-Nitroisoxazole-Based Energetic Materials Full article

Journal

Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052

Output data

Year: 2025, Volume: 27, Pages: 3795–3799 Pages count : DOI: 10.1021/acs.orglett.5c01074

Authors

Konnov Alexey A. ¹ , Lisyutkin Anton D. ^1,2 , Vinogradov Dmitry B. ¹ , Nazarova Amina A. ³ , Pivkina Alla N. ³ , Fershtat Leonid L. ^1,2

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russian Federation
2	National Research University, Higher School of Economics 101000, Myasnitskaya str., 20, Moscow (Russia)
3	N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russian Federation

A set of novel biheterocyclic energetic materials incorporating the 4-nitroisoxazole scaffold was synthesized. Thus, prepared species demonstrated excellent thermal stability (181–244 °C), good densities (1.71–1.74 g·cm–3), and detonation velocities (7.6–8.3 km s–1), while retaining insensitivity to friction. To the best of our knowledge, this is the first example of an incorporation of the 4-nitroisoxazole scaffold into the structure of high-energy materials.

Konnov A.A. , Lisyutkin A.D. , Vinogradov D.B. , Nazarova A.A. , Pivkina A.N. , Fershtat L.L.
Synthesis of 4-Nitroisoxazole-Based Energetic Materials
Organic Letters. 2025. V.27. P.3795–3799. DOI: 10.1021/acs.orglett.5c01074 WOS Scopus OpenAlex

Web of science:	WOS:001456896000001
Scopus:	2-s2.0-105001649961
OpenAlex:	W4409048703

DB	Citing
OpenAlex	8
Web of science	3
Scopus	5