Electrochemical Deaminative Carboxylation of Aryltriazenes with CO2 to Aryl Carboxylic Acids

Electrochemical Deaminative Carboxylation of Aryltriazenes with CO2 to Aryl Carboxylic Acids Научная публикация

Журнал

Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052

Вых. Данные

Год: 2025, Том: 27, Номер: 17, Страницы: 4553–4558 Страниц : DOI: 10.1021/acs.orglett.5c01099

Авторы

Zhao Lan ¹ , Wu An-Guo ¹ , Li Hong-Ru ¹ , Terent’ev Alexander O. ² , He Liang-Nian ¹

Организации

1	State Key Laboratory and Institute of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, Tianjin 300071, P. R. China
2	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospect, Moscow 119991, Russian Federation

The utilization of CO2 as an appealing chemical feedstock for diverse synthetically valuable products is constantly evolving, potentially alleviating chemical production that relies on petrochemistry. Herein we report the first example of the electrochemical deaminative carboxylation of aryltriazenes with CO2. The reaction can be performed under mild and catalyst-free conditions by using sustainable methods with CO2 as a green C1 building block, efficiently converting a diverse range of readily available aryltriazenes into synthetically valuable carboxylic acids. In particular, the formation of C–C bonds by deaminative carboxylation would be an impactful addition to the synthesis toolbox.

Zhao L. , Wu A-G. , Li H-R. , Terent’ev A.O. , He L-N.
Electrochemical Deaminative Carboxylation of Aryltriazenes with CO2 to Aryl Carboxylic Acids
Organic Letters. 2025. V.27. N17. P.4553–4558. DOI: 10.1021/acs.orglett.5c01099 WOS OpenAlex

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