New catalytic organometallic reactions that changed the strategy of organic synthesis Review
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Russian Chemical Reviews
ISSN: 1468-4837 , E-ISSN: 0036-021X |
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| Output data | Year: 2025, Volume: 94, Number: 6, Article number : RCR5172, Pages count : DOI: 10.59761/rcr5172 | ||
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Abstract:
The review integrates, for the first time, the results of studies carried out in the world over the last 15 – 20 years on the development and application of fundamental organometallic reactions catalyzed by transition metal complexes that give new carbon – carbon, metal – carbon, and heteroatom –carbon bonds and on the synthesis of small, medium, and large metallacarbocycles containing main group metals (Mg, Al, B). The review addresses data on the use of new organometallic reactions and metallacarbocycles for the preparation of practically important synthetic analogues of natural compounds, Z,Z-diene and Z,Z,Z-triene unsaturated carboxylic acids, acetogenins, lembehynes, regular isoprenoids, insect pheromones with a record high sterechemical purity, as well as toxins, heterocycles, and biaryls, the synthesis of which by other methods requires the use of expensive reagents or multistep procedures.
Cite:
Dzhemilev U.M.
, D'yakonov V.A.
New catalytic organometallic reactions that changed the strategy of organic synthesis
Russian Chemical Reviews. 2025. V.94. N6. RCR5172 . DOI: 10.59761/rcr5172 WOS Scopus OpenAlex
New catalytic organometallic reactions that changed the strategy of organic synthesis
Russian Chemical Reviews. 2025. V.94. N6. RCR5172 . DOI: 10.59761/rcr5172 WOS Scopus OpenAlex
Identifiers:
| Web of science: | WOS:001518850900003 |
| Scopus: | 2-s2.0-105009594138 |
| OpenAlex: | W4411470030 |