Oxidation of toluene with N2O on ZSM-5 zeolite under supercritical conditions

Oxidation of toluene with N2O on ZSM-5 zeolite under supercritical conditions Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2025, Volume: 35, Number: 3, Pages: 344-346 Pages count : 3 DOI: 10.71267/mencom.7626

Authors

Bogdan Viktor Ignat'evich ¹ , Zholobenko Vladimir Leonidovich ² , Bogdan Tatiana Veniaminovna ^2,1 , Kustov Aleksandr Leonidovich ^2,1 , Koklin Aleksey Evgenievich ¹ , Mishanin Igor Igorevich ¹ , Mashchenko Nikolay V ¹ , Bogorodskiy Sergey Eduardovich ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation

The direct oxidation of toluene to cresols with nitrous oxide as the oxidant was carried out over a ZSM-5 zeolite catalyst under gaseous and supercritical conditions (395 °C and 0.5, 7, 12 MPa; 420 °C and 15 MPa). The supercritical oxidation is characterized by a significantly greater productivity as compared to the gas-phase process. Successful in situ regeneration of the deactivated catalyst during the transition from the gas-phase to the supercritical process has been demonstrated.

Bogdan V.I. , Zholobenko V.L. , Bogdan T.V. , Kustov A.L. , Koklin A.E. , Mishanin I.I. , Mashchenko N.V. , Bogorodskiy S.E.
Oxidation of toluene with N2O on ZSM-5 zeolite under supercritical conditions
Mendeleev Communications. 2025. V.35. N3. P.344-346. DOI: 10.71267/mencom.7626 WOS OpenAlex

Web of science:	WOS:001490937900003
OpenAlex:	W4409003309

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