Radical Substitution of Polyfluoroarenes and Heteroarenes Promoted by Photoredox Activation of Organozinc Iodides

Radical Substitution of Polyfluoroarenes and Heteroarenes Promoted by Photoredox Activation of Organozinc Iodides Full article

Journal

Advanced Synthesis & Catalysis
ISSN: 1615-4169 , E-ISSN: 1615-4150

Output data

Year: 2023, Volume: 365, Number: 19, Pages: 3387-3391 Pages count : 5 DOI: 10.1002/adsc.202300757

Authors

Gladkov Anton ^1,2 , Levin Vitalij ² , Dilman Alexander D. ²

Affiliations

1	Lomonosov Moscow State University Department of Chemistry 119991 Moscow Leninskie Gory 1–3 Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry 119991 Moscow Leninsky prosp. 47 Russian Federation

Aromatic compounds interact with organozinc reagents under photoredox conditions, leading to the substitution products. The reaction is performed under blue light irradiation via in situ generated organozinc reagents (Barbier conditions), which are oxidized by the photocatalyst, followed by radical attack at the aromatic substrate. The method works with polyfluorinated arenes, 2-chlorobenzoxazoles, and 2-sulfonyl-substituted benzothiazole.

Gladkov A. , Levin V. , Dilman A.D.
Radical Substitution of Polyfluoroarenes and Heteroarenes Promoted by Photoredox Activation of Organozinc Iodides
Advanced Synthesis & Catalysis. 2023. V.365. N19. P.3387-3391. DOI: 10.1002/adsc.202300757 WOS Scopus OpenAlex

Web of science:	WOS:001068316800001
Scopus:	2-s2.0-85171640243
OpenAlex:	W4386618711

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