Реферат: Exploration of new possible molecular combinations for the preparation of energetic materials remains a challenging task. Herein, the construction of new azole assemblies incorporating the poorly studied 2,5-disubstituted tetrazole motif in combination with oxadiazole moieties is presented. A complete set of experimentally defined properties including thermal stability and mechanical sensitivity, as well as the calculated detonation performance, was evaluated. All target energetic substances have high densities (1.72–1.74 g cm−3) and high combined nitrogen–oxygen content (55–73%). Azo-bridged hexaheterocyclic entities showed high friction sensitivity (on the level of primary explosives), while the introduction of two amino groups improved the sensitivity up to a nitro ester's level, considered as the lowest acceptable level for manufacturing.

Библиографическая ссылка: Sereda V.A. , Dubasova E.V. , Ananyev I.V. , Kosareva E.K. , Fershtat L.L.
Exploring the energetic potential of 2,5-disubstituted tetrazoles: a case of 2,5-bis(oxadiazolyl)tetrazoles
Dalton Transactions. 2025. V.54. P.8870-8880. DOI: 10.1039/d5dt00685f WOS Scopus OpenAlex

Идентификаторы БД:

Web of science:	WOS:001484350200001
Scopus:	2-s2.0-105004824165
OpenAlex:	W4409957279

Цитирование в БД:

БД	Цитирований
OpenAlex	3
Web of science	2
Scopus	2

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