1,1'-Diphenyl-bis(silatrane) as the First Structurally Characterized bis(silatrane)

1,1'-Diphenyl-bis(silatrane) as the First Structurally Characterized bis(silatrane) Full article

Journal

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Output data

Year: 2022, Volume: 48, Number: 2, Pages: 69-74 Pages count : 6 DOI: 10.1134/s1070328422010079

Authors

Wang Yu. ¹ , Vakhrusheva D.M. ^2,3 , Krylova I.V. ² , Kozmenkova A.Ya. ² , Nikolaevskaya E.N. ² , Mankaev B.N. ⁴ , Minyaev M.E. ² , Syroeshkin M.A. ² , Egorov M.P. ² , Jouikov V.V. ¹

Affiliations

1	University of Rennes 1, UMR CNRS 6226, ISCR (Institut des Sciences Chimiques de Rennes), Rennes, France
2	Zelinsky Institute of Organic Chemistry, Moscow, Russia
3	Higher Chemical College, Russian Academy of Sciences, Mendeleev Russian University of Chemical Technology, Moscow, Russia
4	Moscow State University, Moscow, Russia

1,1'-Diphenyl-bis(silatrane) (I) was obtained by the reaction of tris(1,3-dihydroxypropan-2-yl)amine (L) with PhSi(OEt)3 in toluene. The molecular structure of complex I was established by X-ray diffraction (CIF file CCDC no. 2078347). Study of the redox properties of new bis(silatrane) I demonstrated that its radical ions generated by cyclic voltammetry are stable since the radical center located on the nitrogen atom is sterically protected within the bis(atrane) cage.

Wang Y. , Vakhrusheva D.M. , Krylova I.V. , Kozmenkova A.Y. , Nikolaevskaya E.N. , Mankaev B.N. , Minyaev M.E. , Syroeshkin M.A. , Egorov M.P. , Jouikov V.V.
1,1'-Diphenyl-bis(silatrane) as the First Structurally Characterized bis(silatrane)
Russian Journal of Coordination Chemistry. 2022. V.48. N2. P.69-74. DOI: 10.1134/s1070328422010079 WOS Scopus OpenAlex

Web of science:	WOS:000767800600001
Scopus:	2-s2.0-85126210651
OpenAlex:	W4220667093

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