Electrochemical behavior of bridged 1,2,4-dioxazolidine derivative in acetonitrile medium on the smooth gold

Electrochemical behavior of bridged 1,2,4-dioxazolidine derivative in acetonitrile medium on the smooth gold Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2025, Volume: 35, Number: 4, Pages: 417-419 Pages count : 3 DOI: 10.71267/mencom.7714

Authors

Polyakov Mikhail V. ¹ , Vedenyapina Marina Dmitrievna ¹ , Skundin Aleksandr Mordukhaevich ² , Yaremenko Ivan Andreevich ¹ , Radulov Peter Sergeyevich ¹ , Belyakova Yulia Yuryevna ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, Russian Federation

Bridged bicyclic peroxide with 1,2,4-dioxazolidine core, namely, ethyl 2-(4-chlorobenzyl)-1,5-dimethyl-6,7-dioxa-8- azabicyclo[3.2.1]octane-2-carboxylate, was studied by cyclic voltammetry in acetonitrile medium on a smooth gold electrode. During the cathode process, two electrons are transferred, with the first electron transfer being reversible; a mechanism of cathode reduction of the substrate involves acetonitrile as the source of protons. The anodic oxidation involves the formation of colloidal gold particles due to corrosion of the gold electrode.

Polyakov M.V. , Vedenyapina M.D. , Skundin A.M. , Yaremenko I.A. , Radulov P.S. , Belyakova Y.Y.
Electrochemical behavior of bridged 1,2,4-dioxazolidine derivative in acetonitrile medium on the smooth gold
Mendeleev Communications. 2025. V.35. N4. P.417-419. DOI: 10.71267/mencom.7714 WOS Scopus OpenAlex

Web of science:	WOS:001501925500014
Scopus:	2-s2.0-105007448193
OpenAlex:	W4410575330

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