Synthesis and Evaluation of Silicon‐Containing Acridine Photocatalysts

Synthesis and Evaluation of Silicon‐Containing Acridine Photocatalysts Full article

Journal

ChemPhotoChem
ISSN: 2367-0932

Output data

Year: 2025, Volume: 9, Number: 9, Article number : e202500138, Pages count : DOI: 10.1002/cptc.202500138

Authors

Kupriyanets Liubov O. ^1,2 , Zubkov Mikhail O. ² , Kosobokov Mikhail D. ² , Dilman Alexander D. ²

Affiliations

1	Department of Chemistry Lomonosov Moscow State University Leninskie Gory 1‐3 Moscow 119991 Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry Leninsky prosp. 47 Moscow 119991 Russian Federation

A protocol for the synthesis of sterically hindered 9-silylacridines via lithiation/silylation sequence is developed. The photocatalytic efficiency of obtained acridines is tested in a variety of decarboxylative processes and compared with the properties of aryl- and alkyl-substituted analogs. To explain the observations, quantum chemical calculations are carried out, revealing the features of the spatial structures of these molecules.

Kupriyanets L.O. , Zubkov M.O. , Kosobokov M.D. , Dilman A.D.
Synthesis and Evaluation of Silicon‐Containing Acridine Photocatalysts
ChemPhotoChem. 2025. V.9. N9. e202500138 . DOI: 10.1002/cptc.202500138 OpenAlex

OpenAlex:

W4411769763

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