Photocatalytic Alkene Hydrofunctionalization with Benzoic Esters of Fluorinated Alcohols Mediated by Tin(II) Chloride

Photocatalytic Alkene Hydrofunctionalization with Benzoic Esters of Fluorinated Alcohols Mediated by Tin(II) Chloride Научная публикация

Журнал

Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052

Вых. Данные

Год: 2025, Том: 27, Номер: 34, Страницы: 9506-9510 Страниц : 5 DOI: 10.1021/acs.orglett.5c03013

Авторы

Lunkov Sergey S. ¹ , Malakhova Ekaterina V. ^2,1 , Levin Vitalij V. ¹ , Dilman Alexander D. ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation
2	Higher Chemical College, D. Mendeleev University of Chemical Technology of Russia, Miusskaya sq. 9, 125047 Moscow, Russian Federation

A method for the hydrofluoroalkylation of alkenes with the benzoic ester of 3,3,3-trifluorolactate and bis(trifluoromethyl)-substituted alcohols is described. The reaction is performed with N-phenylphenothiazine photocatalyst and has high tolerance toward functional groups. A key feature of the method is the use of tin(II) chloride/toluenesulfonic acid as a stoichiometric reducing agent.

Lunkov S.S. , Malakhova E.V. , Levin V.V. , Dilman A.D.
Photocatalytic Alkene Hydrofunctionalization with Benzoic Esters of Fluorinated Alcohols Mediated by Tin(II) Chloride
Organic Letters. 2025. V.27. N34. P.9506-9510. DOI: 10.1021/acs.orglett.5c03013 WOS OpenAlex

Web of science:	WOS:001553224500001
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