Azides as an unconventional source of iminyl radicals: electrochemically induced synthesis of

Azides as an unconventional source of iminyl radicals: electrochemically induced synthesis of Full article

Journal

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Output data

Year: 2025, Volume: 61, Pages: 14426-14429 Pages count : 4 DOI: 10.1039/d5cc03556b

Authors

Paveliev Stanislav A ¹ , Dvoretskiy Andrey ¹ , Segida Oleg O ¹ , Krylov Igor B ¹ , Terent'ev Alexander O ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, 47 Leninsky Prosp., Moscow 119991, Russian Federation. alterex@yandex.ru.

Electrochemically induced synthesis of O-imido oximes from benzyl azides and N-hydroxyimides via N–O coupling has been discovered. The developed approach reveals a new role of benzyl azides in the practice of organic synthesis as precursors of iminyl radicals for intermolecular coupling reactions. The method is applicable to a wide range on benzyl azides and N-hydroxyimides, and O-imido oximes are obtained in yields up to 94%.

Paveliev S.A. , Dvoretskiy A. , Segida O.O. , Krylov I.B. , Terent'ev A.O.
Azides as an unconventional source of iminyl radicals: electrochemically induced synthesis of
Chemical Communications. 2025. V.61. P.14426-14429. DOI: 10.1039/d5cc03556b WOS OpenAlex

Web of science:	WOS:001563096100001
OpenAlex:	W4413972549

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