Development of cationic gallium phthalocyanine catalysts for the chemistry of donor-acceptor cyclopropanes and its reactions with aldehydes

Development of cationic gallium phthalocyanine catalysts for the chemistry of donor-acceptor cyclopropanes and its reactions with aldehydes Full article

Journal

Molecular Catalysis
ISSN: 2468-8231 , E-ISSN: 2468-8274

Output data

Year: 2023, Volume: 550, Article number : 113480, Pages count : DOI: 10.1016/j.mcat.2023.113480

Authors

Levina Anastasia A. ¹ , Novikov Roman A. ¹ , Borisov Denis D. ¹ , Novikov Maxim A. ¹ , Tomilov Yury V. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation

Cationic gallium phthalocyanine (RPcGa+) catalysts with SbF6– and Sb2F11–/Sb3F16– weakly coordinating anions were developed and used in the catalytic chemistry of donor-acceptor (D–A) cyclopropanes and related substrates. For the first time, these processes were implemented on the examples of [3 + 2]-cycloaddition/annulation reactions of D–A cyclopropanes and styrylmalonates with various aldehydes, as well as some other transformations with different substrates.

Levina A.A. , Novikov R.A. , Borisov D.D. , Novikov M.A. , Tomilov Y.V.
Development of cationic gallium phthalocyanine catalysts for the chemistry of donor-acceptor cyclopropanes and its reactions with aldehydes
Molecular Catalysis. 2023. V.550. 113480 . DOI: 10.1016/j.mcat.2023.113480 WOS Scopus OpenAlex

≡ Web of science:	WOS:001082321500001
≡ Scopus:	2-s2.0-85172007214
≡ OpenAlex:	W4386941047