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Efficient performance of the Pd1Cun/Al2O3 catalyst in front-end acetylene hydrogenation Full article

Journal Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436
Output data Year: 2025, Volume: 35, Number: 6, Pages: 711-713 Pages count : 3 DOI: 10.71267/mencom.7850
Authors Mashkovsky Igor' Sergeevich 1 , Markov Pavel Viktorovich 1 , Baeva Galina Nikolaevna 1 , Vaulina Anastasia Evgenievna 2,1 , Smirnova Nadezhda Sergeevna 1 , Melnikov Dmitry Petrovich 1,3 , Stakheev Aleksandr Yurevich 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2 D. I. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russian Federation
3 National University of Oil and Gas ‘Gubkin University’, 119991 Moscow, Russian Federation

Abstract: Single-atom Pd1Cun/Al2O3 catalysts were studied in front-end acetylene hydrogenation. It was found that the selectivity to ethylene increases sharply as the Pd : Cu ratio changes from 1 : 1 to 1 : 10. Single-atom PdCu/Al2O3 catalysts demonstrate remarkable resistance to CO swings and retain high selectivity in its absence, which are crucial for industrial applications.
Cite: Mashkovsky I.S. , Markov P.V. , Baeva G.N. , Vaulina A.E. , Smirnova N.S. , Melnikov D.P. , Stakheev A.Y.
Efficient performance of the Pd1Cun/Al2O3 catalyst in front-end acetylene hydrogenation
Mendeleev Communications. 2025. V.35. N6. P.711-713. DOI: 10.71267/mencom.7850 WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:001629936900006
Scopus: 2-s2.0-105021380490
OpenAlex: W4415383316
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