Synthesis of functionalized aminomethylene bisorganophosphorus acids

Synthesis of functionalized aminomethylene bisorganophosphorus acids Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2025, Volume: 74, Number: 10, Pages: 3061-3075 Pages count : 15 DOI: 10.1007/s11172-025-4786-0

Authors

Bubnov Yu.N. ^1,2 , Prishchenko A.A. ^1,3 , Livantsov M.V. ³ , Novikova O.P. ³ , Livantsova L.I. ³ , Baranin S.V. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Build. 1, 28 ul. Vavilova, 119991, Moscow, Russian Federation
3	Chemical Department, Lomonosov Moscow State University, Build. 3, 1 Leninskiye Gory, 119991, Moscow, Russian Federation

Convenient syntheses of functionalized aminomethylene bisorganophosphorus acids and their derivatives have been developed. Trimethylsilyl esters of trivalent phosphorus acids react with iminium salts in the presence of effective catalysts, trimethylsilyl triflate or boron trifluoride etherate, to afford new functionalized aminomethylene bisorganophosphorus acids and their derivatives with P—C—P units. The resulting substances, organophosphorus analogs of amino carboxylic acids and natural pyrophosphates containing various functional groups are structural analogs of active plant growth regulators and can be of interest as biologically active substances and effective polydentate ligands.

Bubnov Y.N. , Prishchenko A.A. , Livantsov M.V. , Novikova O.P. , Livantsova L.I. , Baranin S.V.
Synthesis of functionalized aminomethylene bisorganophosphorus acids
Russian Chemical Bulletin. 2025. V.74. N10. P.3061-3075. DOI: 10.1007/s11172-025-4786-0 WOS Scopus OpenAlex

≡ Web of science:	WOS:001618041200015
≡ Scopus:	2-s2.0-105022408555
≡ OpenAlex:	W7105997893