2-Fluoroanthraquinone-catalyzed photooxidation of benzylic alcohols and aliphatic diols in supercritical carbon dioxide

2-Fluoroanthraquinone-catalyzed photooxidation of benzylic alcohols and aliphatic diols in supercritical carbon dioxide Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2026, Volume: 36, Number: 1, Pages: 47-49 Pages count : 3 DOI: 10.71267/mencom.7855

Authors

Merkulov Vladislav G. ¹ , Ivanova Elizaveta A. ¹ , Rusakov Savva P. ¹ , Zharkov Mikhail N. ¹ , Zlotin Sergei G. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Benzylic alcohols are oxidized with molecular oxygen to the corresponding carbonyl compounds and carboxylic acids in supercritical carbon dioxide medium in the presence of 2-fluoroanthraquinone as an organic photocatalyst. The transformation is promoted by blue light irradiation at 405 nm. The similar processing of aliphatic terminal 1,3- and 1,4-diols affords the corresponding diacids, while small changes in the procedure allows one to convert butane-1,4-diol into γ-butyrolactone in one experimental step.

Merkulov V.G. , Ivanova E.A. , Rusakov S.P. , Zharkov M.N. , Zlotin S.G.
2-Fluoroanthraquinone-catalyzed photooxidation of benzylic alcohols and aliphatic diols in supercritical carbon dioxide
Mendeleev Communications. 2026. V.36. N1. P.47-49. DOI: 10.71267/mencom.7855 WOS OpenAlex

Web of science:	WOS:001629991500013
OpenAlex:	W4416804581

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