Synthesis of functionalized furan-containing phosphonous and phosphinic acids

Synthesis of functionalized furan-containing phosphonous and phosphinic acids Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2023, Volume: 72, Number: 9, Pages: 2138-2147 Pages count : 10 DOI: 10.1007/s11172-023-4009-5

Authors

Prishchenko A.A. ¹ , Livantsov M.V. ¹ , Novikova O.P. ¹ , Livantsova L.I. ¹ , Baranin S.V. ² , Bubnov Yu.N. ^3,2

Affiliations

1	Chemical Department, M. V. Lomonosov Moscow State University, Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
3	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation

A convenient synthesis of functionalized furan-containing phosphonous and phosphinic acids has been developed. The radical addition of bis(trimethylsiloxy)phosphine to 2-vinylfuran and trimethylsilyl 3-(2-furyl)acrylate proceeds regioselectively to afford new 2-furyl-substituted alkylphosphonites, the subsequent aminomethylation and carboxyethylation of which give various target phosphinic acids.

Prishchenko A.A. , Livantsov M.V. , Novikova O.P. , Livantsova L.I. , Baranin S.V. , Bubnov Y.N.
Synthesis of functionalized furan-containing phosphonous and phosphinic acids
Russian Chemical Bulletin. 2023. V.72. N9. P.2138-2147. DOI: 10.1007/s11172-023-4009-5 WOS Scopus OpenAlex

≡ Web of science:	WOS:001074328300020
≡ Scopus:	2-s2.0-85172339499
≡ OpenAlex:	W4387053735