Bis(1,2,4-triphenylcyclopentadienyl) Terbium 4,4,4-trifluoro-1-phenylbutane-1,3-dionate

Bis(1,2,4-triphenylcyclopentadienyl) Terbium 4,4,4-trifluoro-1-phenylbutane-1,3-dionate Full article

Journal

Molbank
ISSN: 1422-8599

Output data

Year: 2025, Volume: 2025, Number: 4, Article number : M2102, Pages count : DOI: 10.3390/m2102

Authors

Bardonov Daniil A. ^1,2 , Minyaev Mikhail E. ³ , Puntus Lada N. ^1,4,5 , Nifant’ev Ilya E. ^1,6 , Roitershtein Dmitrii M. ^1,3,2

Affiliations

1	A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991 Moscow, Russia
2	National Research University Higher School of Economics, 20 Miasnitskaya Str., 101000 Moscow, Russia
3	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospect, 119991 Moscow, Russia
4	G. V. Plekhanov Russian University of Economics, 117997 Moscow, Russia
5	V. A. Kotel’nikov Institute of Radioengineering and Electronics, Russian Academy of Sciences, Fryazino, 141190 Moscow, Russia
6	Chemistry Department, M.V. Lomonosov Moscow State University, 1 Leninskie Gory Str., Building 3, 119991 Moscow, Russia

A new bis(cyclopentadienyl) terbium(III) complex with 1,2,4-triphenylcyclopentadienyl and 4,4,4-trifluoro-1-phenylbutane-1,3-dionate ligands was synthesized. Single-crystal X-ray analysis revealed a mononuclear bis(cyclopentadienyl) complex with a diketonate ligand in the bisector plane. The compound under study exhibits a ligand ligand charge transfer state (LLCT), according to optical spectroscopy and crystallographic data.

Bardonov D.A. , Minyaev M.E. , Puntus L.N. , Nifant’ev I.E. , Roitershtein D.M.
Bis(1,2,4-triphenylcyclopentadienyl) Terbium 4,4,4-trifluoro-1-phenylbutane-1,3-dionate
Molbank. 2025. V.2025. N4. M2102 . DOI: 10.3390/m2102 WOS Scopus OpenAlex

≡ Web of science:	WOS:001646987000001
≡ Scopus:	2-s2.0-105025658098
≡ OpenAlex:	W4417124795