Electrochemical Synthesis of Methoxy-NNO-azoxy Compounds via N=N Bond Formation Between Ammonium N-(methoxy)nitramide and Nitroso Compounds

Electrochemical Synthesis of Methoxy-NNO-azoxy Compounds via N=N Bond Formation Between Ammonium N-(methoxy)nitramide and Nitroso Compounds Full article

Journal

Molecules
ISSN: 1420-3049

Output data

Year: 2025, Volume: 30, Number: 24, Article number : 4723, Pages count : DOI: 10.3390/molecules30244723

Authors

Budnikov Alexander S. ¹ , Kulikov Andey A. ¹ , Klenov Michael S. ¹ , Leonov Nikita E. ¹ , Krylov Igor B. ¹ , Terent’ev Alexander O. ¹ , Tartakovsky Vladimir A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prosp., 119991 Moscow, Russia

In this study, atom- and step-efficient electrochemical coupling of nitroso compounds with ammonium N-(methoxy)nitramide, furnishing methoxy-NNO-azoxy compounds, is reported. The developed protocol employs a divided electrochemical cell, proceeds under constant-current electrolysis conditions, and is applicable to aromatic, heterocyclic, and aliphatic nitroso compounds. The versatility of the developed electrochemical coupling method was demonstrated by comparing it with chemical approaches on various substrates.

Budnikov A.S. , Kulikov A.A. , Klenov M.S. , Leonov N.E. , Krylov I.B. , Terent’ev A.O. , Tartakovsky V.A.
Electrochemical Synthesis of Methoxy-NNO-azoxy Compounds via N=N Bond Formation Between Ammonium N-(methoxy)nitramide and Nitroso Compounds
Molecules. 2025. V.30. N24. 4723 . DOI: 10.3390/molecules30244723 OpenAlex

OpenAlex:

W4417198466

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