High-nuclearity Cu 14 ionic complex featuring 1,3-bis(diphenylphosphino)propane and methylsilsesquioxane ligands: highly efficient catalysis of mild peroxidative alkane fuctionalizations

High-nuclearity Cu 14 ionic complex featuring 1,3-bis(diphenylphosphino)propane and methylsilsesquioxane ligands: highly efficient catalysis of mild peroxidative alkane fuctionalizations Научная публикация

Журнал

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Вых. Данные

Год: 2026, Том: 62, Номер: 1, Страницы: 181-184 Страниц : 4 DOI: 10.1039/d5cc05805h

Авторы

Arteev Ivan S. ^1,2,3 , Khrustalev Victor N. ^2,3 , Shul’pina Lidia S. ¹ , Rodionov Alexey N. ¹ , Shubina Elena S. ¹ , Ragimov Karim ⁴ , Wang Zhi ⁵ , Bilyachenko Alexey N. ¹

Организации

1	A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences (INEOS RAS), Vavilov St. 28, 119991 Moscow, Russian Federation
2	Peoples’ Friendship University of Russia (RUDN University), Miklukho-Maklaya St. 6, 117198 Moscow, Russian Federation
3	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospect, 119991 Moscow, Russian Federation
4	Baku State University, Z. Xalilov Str. 23, Az 1148 Bak, Azerbaijan
5	Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong, 250100, China

Информация о финансировании (1)

Институт органической химии им. Н. Д. Зелинского Российской академии наук

The first metallacomplex containing both 1,3-bis(diphenylphosphino)propane and silsesquoxane ligands is presented, which adopts an intriguing three-component ionic structure. According to X-ray diffraction studies, the central dianionic CuII12-methylsilsesquioxane cage is balanced by two external cationic [CuI(dppp)2] species, giving a total Cu14 nuclearity. The cage component of the complex encapsulates hydroxyl, carbonate, and chloride species. The complex was evaluated as a catalyst for the effective oxidation of alkanes to alkyl hydroperoxides and of alcohols to ketones using peroxides.

Arteev I.S. , Khrustalev V.N. , Shul’pina L.S. , Rodionov A.N. , Shubina E.S. , Ragimov K. , Wang Z. , Bilyachenko A.N.
High-nuclearity Cu 14 ionic complex featuring 1,3-bis(diphenylphosphino)propane and methylsilsesquioxane ligands: highly efficient catalysis of mild peroxidative alkane fuctionalizations
Chemical Communications. 2026. V.62. N1. P.181-184. DOI: 10.1039/d5cc05805h WOS Scopus OpenAlex

Web of science:	WOS:001624998700001
Scopus:	2-s2.0-105022873570
OpenAlex:	W4416767753

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