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Triazine derivatives as metal-free electrocatalysts: do three nitrogen atoms mimic a metal? Научная публикация

Журнал Sustainable Energy & Fuels
ISSN: 2398-4902
Вых. Данные Год: 2025, Том: 9, Номер: 6, Страницы: 1464-1479 Страниц : 16 DOI: 10.1039/d4se01751j
Авторы Lebedeva Olga 1 , Kultin Dmitry 1 , Zakharov Valery 1 , Kuznetsova Irina 1 , Aslanov Leonid 1 , Kustov Leonid 1,2,3
Организации
1 Department of Chemistry, Lomonosov Moscow State University, Moscow, Russia
2 Institute of Ecology and Engineering, National Science and Technology University “MISiS”, Leninsky Prospect 4, Moscow, Russia
3 N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, Moscow, Russia

Реферат: Environmental changes and climate concerns dictate the necessary transition to sustainable technologies based on green reactions. At the same time, catalysts for carbon dioxide reduction, nitrogen fixation and other electrochemical reactions should be cheap and stable, while exhibiting high selectivity and efficiency. Electrocatalytic reactions make it possible to obtain industrial products under ambient conditions, but this is still difficult and expensive. In the last few years, tremendous progress has been made in the study and application of triazine-based frameworks as catalytic systems and beyond without the use of expensive metals. This short perspective review mainly examines studies not older than five years (more than 75% of citations), with special emphasis being placed on the analysis of the latest research over the last two years (more than 30% of citations). It has been shown that the use of triazines is effective in the reactions of hydrogen evolution (HER), water splitting, oxygen evolution (OER), CO2 reduction (CO2RR), ammonia production (NO3RR and NRR), etc. Based on this analysis, conclusions are drawn about the effectiveness of catalysts and the ways to increase their efficiency. In the near future, we should expect a breakthrough in increasing the hydrophilicity and porosity of triazine catalyst samples, as well as in the use of media in the form of ionic liquids and machine learning and computer modeling of electrode designs.
Библиографическая ссылка: Lebedeva O. , Kultin D. , Zakharov V. , Kuznetsova I. , Aslanov L. , Kustov L.
Triazine derivatives as metal-free electrocatalysts: do three nitrogen atoms mimic a metal?
Sustainable Energy & Fuels. 2025. V.9. N6. P.1464-1479. DOI: 10.1039/d4se01751j WOS Scopus OpenAlex
Идентификаторы БД:
Web of science: WOS:001413259600001
Scopus: 2-s2.0-86000724621
OpenAlex: W4406759990
Цитирование в БД:
БД Цитирований
OpenAlex 7
Scopus 6
Web of science 7
Альметрики: