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Salts of ethylenediamine and diethylenetriamines: modeling of crystal structure and estimation of enthalpies of formation Full article

Journal Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285
Output data Year: 2025, Volume: 74, Number: 2, Pages: 354-360 Pages count : 7 DOI: 10.1007/s11172-025-4527-4
Authors Khakimov D.V. 1 , Pivina T.S. 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

Abstract: Based on quantum chemistry methods and atom-atom potentials, the molecular and crystal structures of a number of salts of diamines and triamines (ethylenediamine, diethylenetriamine, 4-methyldiethylenetriamine, and 4-nitrodiethylenetriamine) were modeled. New polymorphic modifications of salts were predicted. The thermochemical parameters of the compounds were assessed. The calculated enthalpies of formation in the solid phase coincide well with the experimental data known for some compounds.
Cite: Khakimov D.V. , Pivina T.S.
Salts of ethylenediamine and diethylenetriamines: modeling of crystal structure and estimation of enthalpies of formation
Russian Chemical Bulletin. 2025. V.74. N2. P.354-360. DOI: 10.1007/s11172-025-4527-4 WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:001455386500014
Scopus: 2-s2.0-105001246716
OpenAlex: W4408973434
Citing:
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OpenAlex 2
Scopus 1
Web of science 1
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