Synthesis of functionalized hydroxymethyl-substituted organophosphorus acids

Synthesis of functionalized hydroxymethyl-substituted organophosphorus acids Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2025, Volume: 74, Number: 8, Pages: 2427-2448 Pages count : 22 DOI: 10.1007/s11172-025-4724-1

Authors

Bubnov Yu.N. ^1,2 , Prishchenko A.A. ³ , Livantsov M.V. ³ , Novikova O.P. ³ , Livantsova L.I. ³ , Baranin S.V. ²

Affiliations

1	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Build. 1, 28 ul. Vavilova, 119991, Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
3	Chemical Department, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskiye Gory, 119991, Moscow, Russian Federation

Convenient syntheses of functionalized hydroxymethyl-substituted organophosphorus acids and their derivatives have been developed. Trimethylsilyl esters of trivalent phosphorus acids react with various aldehydes and ketones to give new hydroxymethyl-substituted phosphonous, phosphonic and phosphinic acids with P—C—O units. The resulting compounds are of interest as promising biologically active substances, water-soluble polydentate ligands, and effective extractants.

Bubnov Y.N. , Prishchenko A.A. , Livantsov M.V. , Novikova O.P. , Livantsova L.I. , Baranin S.V.
Synthesis of functionalized hydroxymethyl-substituted organophosphorus acids
Russian Chemical Bulletin. 2025. V.74. N8. P.2427-2448. DOI: 10.1007/s11172-025-4724-1 WOS Scopus OpenAlex

≡ Web of science:	WOS:001574171100006
≡ Scopus:	2-s2.0-105016215367
≡ OpenAlex:	W4414142242